학술논문
Electrochemical Dehydrogenative Phosphorylation of Thiols
Document Type
Article
Source
Organic Letters; October 2019, Vol. 21 Issue: 19 p7833-7836, 4p
Subject
Language
ISSN
15237060; 15237052
Abstract
We report herein a new approach for the synthesis of organothiophosphates from phosphonates and thiols through electrochemical reaction. The reactions were conducted without the addition of oxidant, transition-metal base, or base at room temperature. This system has a good substrate scope and functional group tolerance. Aryl and alkyl thiols worked well with phosphonates to afford the corresponding organothiophosphates in good yields.