부산대학교 도서관

Constructing heterostructures is a promising strategy to improve the photoelectrochemical (PEC) performance of photoanodes in PEC water‐splitting systems. The effect on PEC performance is dependent on the deposition conditions of the overlayer in the heterostructured photoanode. Herein, the deposition condition of the antimony selenide (Sb2Se3) overlayer by adjusting the duty cycle and cycle number during pulse‐reverse electrodeposition. This aims to assess its impact on the PEC characteristics of the Sb2Se3overlayered titanium dioxide (Sb2Se3/TiO2) nanotube photoanode. Adequate pulse‐off time in the duty cycle ensures sufficient permeation of deposition electrolyte into the inner wall of TiO2nanotube, leading to uniform Sb2Se3deposition. On the other hand, an excessive cycle number negatively affects PEC performance, as Sb2Se3agglomeration blocks the pores of the TiO2nanotube. Consequently, the Sb2Se3/TiO2nanotube photoanode, when fabricated with the optimal pulse‐off time and cycle number, exhibits enhanced PEC performance. This is due to efficient charge transfer/separation facilitated by the p–n heterojunction and improved light absorption. These insights offer valuable guidance in choosing the appropriate fabrication processes for heterostructured photoanodes in efficient PEC water‐splitting systems. Optimization of the heterojunction effect for the Sb2Se3/TiO2nanotube photoanode with improved photoelectrochemical performance by modulating the pulse‐off time of the duty cycle and the cycle number during the pulse‐reverse electrodeposition of the Sb2Se3overlayer are studied.