학술논문
Clemmensen Reduction. XI. Fragmentation Reactions of Some 3-Acetylcycloalkanones
Document Type
Article
Author
Source
Australian Journal of Chemistry; 1995, Vol. 48 Issue: 11 p1827-1834, 8p
Subject
Language
ISSN
00049425; 14450038
Abstract
Clemmensen reduction of a series of 3-acetylcycloalkanones yields, as the major product, an acyclic unsaturated ketone, the product of fragmentation. Some normal carbonyl-methylene reduction also occurs. A mechanistic rationale for the fragmentation is advanced.