학술논문
Molecular excitations and the quantum adiabatic phase for a nuclear spin
Document Type
Article
Author
Source
Molecular Physics; June 1989, Vol. 67 Issue: 2 p271-279, 9p
Subject
Language
ISSN
00268976; 13623028
Abstract
The effect of chemical shielding on the quantum adiabatic phase factor for a nuclear spin in a molecule is studied. The electronic state dependence of the shielding is shown to produce geometrical relative phase shifts among the eigenfunction components of a nonstationary electronic state. The results are illustrated for two simple systems, a prolate oscillator and asymptotically separated H2+.