학술논문

Adsorptive modelling of toxic cations and ionic dyes onto cellulosic extract
Document Type
Article
Source
Modeling Earth Systems and Environment; December 2016, Vol. 2 Issue: 4 p1-15, 15p
Subject
Language
ISSN
23636203; 23636211
Abstract
This work reports the abstractive potential of Parkia Biglobosaseed waste (PSW) and Parkia Biglobosacellulosic extract (PBCE) for the removal of Cr(VI), Pb(II), methylene blue (MB) and congo red (CR) from aqua system. Physicochemical analyses carried out for these biomaterials were proximate analysis, Fourier transform infra red (FTIR) Spectrophotometry and scanning electron microscopy (SEM). The FTIR data showed that –O–H, –C=C–, –C=O, –C≡C– and –S–H functional groups were responsible for the sequestration of Cr(VI), Pb(II), MB and CR from aqua system. The equilibrium data fitted best to Langmuir isotherm model with the highest adsorption obtained for MB, being 1498.42 mg/g at 298 K and 403.23 mg/g at 298 K for PSW and PBCE respectively. Pseudo-second order model gave the best fits for the kinetic data among two other kinetic models used. The PSW and PBCE biomaterials demonstrated good potentials for the removal of toxic Cr(VI), Pb(II), MB and CR from aqua systems.