학술논문
The mixed-metal tris-(di-sulfide) thio-phosphate, KNb1.77Ta0.23PS10.
Document Type
Academic Journal
Author
Lee Y; Division of Energy Systems Research and Department of Chemistry, Ajou University, Suwon 443-749, Republic of Korea.; Yoon W; Division of Energy Systems Research and Department of Chemistry, Ajou University, Suwon 443-749, Republic of Korea.; Yun H; Division of Energy Systems Research and Department of Chemistry, Ajou University, Suwon 443-749, Republic of Korea.
Source
Publisher: Wiley-Blackwell Country of Publication: United States NLM ID: 101089178 Publication Model: eCollection Cited Medium: Print ISSN: 1600-5368 (Print) Linking ISSN: 16005368 NLM ISO Abbreviation: Acta Crystallogr Sect E Struct Rep Online Subsets: PubMed not MEDLINE
Subject
Language
English
ISSN
1600-5368
Abstract
The title compound catena-poly[potassium [tri-μ-disulfido-μ-tetra-thiophos-pha-to-di[niobate(IV)/tantalate(IV)(0.885/0.115)]]], has been obtained through the reaction of the elements with KCl. The title compound is isostructural with KNb2PS10, with the Nb sites occupied by statistically disordered Nb (88.5%) and Ta (11.5%) atoms. The structure is composed of anionic ∞ (1)[M 2PS10](-) chains along [100] (M = Nb/Ta) and K(+) ions. This chain is built up from distorted bicapped trigonal prisms [MS8] and [PS4] tetra-hedra. There are no inter-chain bonding inter-actions, except for electrostatic and van der Waals forces. The S2 (2-) and S(2-) anionic species and the M (4+)-M (4+) pair [M-M = 2.8939 (3) Å] are observed. The classical charge balance is represented by [K(+)][M (4+)]2[PS4 (3-)][S2 (2-)]3.