학술논문

Contamination level, spatial distribution, and sources of potentially toxic elements in indoor settled household dusts in Tehran, Iran.
Document Type
Academic Journal
Author
Khajooee N; Department of Environmental Science and Engineering, West Tehran Branch, Islamic Azad University, Tehran, Iran.; Modabberi S; School of Geology, College of Science, University of Tehran, Tehran, Iran. modabberi@ut.ac.ir.; Khoshmanesh Zadeh B; Department of Environmental Science and Engineering, West Tehran Branch, Islamic Azad University, Tehran, Iran.; Razavian F; Department of Environmental Science and Engineering, West Tehran Branch, Islamic Azad University, Tehran, Iran.; Gayà-Caro N; Laboratory of Toxicology and Environmental Health, School of Medicine, IISPV, Universitat Rovira i Virgili, Sant Llorenç 21, 43201, Reus, Catalonia, Spain.; Institut d'Investigació Sanitària Pere Virgili (IISPV), 43204, Reus, Catalonia, Spain.; Center of Environmental, Food and Toxicological Technology - TecnATox, Universitat Rovira i Virgili, Tarragona, Spain.; Sierra J; Faculty of Pharmacy, Universitat de Barcelona, Joan XXIII s/n Avenue, 08028, Barcelona, Catalonia, Spain.; Center of Environmental, Food and Toxicological Technology - TecnATox, Universitat Rovira i Virgili, Tarragona, Spain.; Rovira J; Laboratory of Toxicology and Environmental Health, School of Medicine, IISPV, Universitat Rovira i Virgili, Sant Llorenç 21, 43201, Reus, Catalonia, Spain.; Institut d'Investigació Sanitària Pere Virgili (IISPV), 43204, Reus, Catalonia, Spain.; Environmental Engineering Laboratory, Departament d'Enginyeria Química, Universitat Rovira i Virgili, Paisos Catalans Avenue 26, 43007, Tarragona, Catalonia, Spain.; Center of Environmental, Food and Toxicological Technology - TecnATox, Universitat Rovira i Virgili, Tarragona, Spain.
Source
Publisher: Kluwer Academic Publishers Country of Publication: Netherlands NLM ID: 8903118 Publication Model: Electronic Cited Medium: Internet ISSN: 1573-2983 (Electronic) Linking ISSN: 02694042 NLM ISO Abbreviation: Environ Geochem Health Subsets: MEDLINE
Subject
Language
English
Abstract
Tehran, the capital city of Iran, has been facing air pollution for several decades due to rapid urbanization, population growth, improper vehicle use, and the low quality of fuels. In this study, 31 indoor dust samples were collected passively from residential and commercial buildings located in the central and densely populated districts of the city. These samples were analyzed after preparation to measure the concentration of elements (As, Be, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Se, Sr, V, Zn). Statistical data analyses were employed to compare their relationship across various uses, variations, and for source identification. Geochemical indices of contamination factor (CF) and pollution load index (PLI) were utilized to evaluate the degree of contamination. The mean concentrations of Zn, Cu, and Pb (938, 206, and 176 µg g -1 , respectively) are 6, 5, and 3 times higher than their mean values in worldwide urban soils. Additionally, Cd, Mo, and Ni showed concentrations about 1.5 times higher, while As, Co, Cr, Mn, and Sr fell within the range of reference soils. Be, V, and Sb displayed remarkably lower mean values. Building use did not significantly influence element levels in indoor deposited dust except for Pb and Zn. A comparison of indoor concentrations with previously published data for outdoor dusts revealed higher enrichments of Mo, Cu, Pb, and Ni, while As, Cd, and Zn showed lower enrichments in street dust samples. The order of CF values indicated Hg > Zn > Cd > Pb > Cu > As > Ni > Cr > Co > V. For Hg, Zn, Pb, Cd, and Cu, all or almost all samples exhibited very high contamination. PLI values were consistently higher than 1, indicating contamination in all samples. Multivariate statistical analysis and Tehran's specific geological location suggested that mafic-intermediate volcanic rocks are primary sources for Cr, Cu, Fe, and Ni (PC1). As, Pb, and V (PC2) were attributed to fossil fuel combustion in vehicles and residential buildings. Pb is a legacy metal remaining from the use of leaded gasoline, which was phased out in the 1990s. Zn (PC3) is derived from vehicle tires.
(© 2024. The Author(s), under exclusive licence to Springer Nature B.V.)