부산대학교 도서관

Efficient conversion of lignin depolymerization products to more stable chemicals has attracted increasing attention during last few years. Here, we reported a novel and efficient method for lignin depolymerization products valorization on the simple and economic catalyst Ni x Mg 1 − x O. In which, the unsaturated ingredients were converted to thermal and chemical stable products, resulting in the obvious decreasing of the unsaturated degree of the products and the repolymerization of the phenolic oligomer. The results showed that more than 98% of phenol, a model chemical of lignin depolymerization products, could be converted to cyclohexanol with 100% selectivity. Further investigation demonstrated that it was also efficient for the real lignin depolymerization products, where a significant decrease on the oxygen content and the average molecular weight were shown. Moreover, the Ni x Mg 1 − x O catalyst was recyclable, and no significant loss of the catalytic activity was exhibited even after 5 runs. [ABSTRACT FROM AUTHOR]