학술논문
New aromatization pathway of 2,3-dihydropyridines by the action of superbase: Concurrent synthesis of 2-(methylsulfanyl)-6-[(vinyloxy)methyl]pyridine and 3-methoxy-6-methyl-2-(methylsulfanyl)pyridine.
Document Type
Article
Author
Source
Subject
*AROMATIZATION
*DIHYDROPYRIDINE
*SUPERBASES (Chemistry)
*PYRIDINE
*METHOXY group
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*
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Language
ISSN
1070-4280
Abstract
Aromatization of 5-methoxy-6-(methylsulfanyl)-2-[(vinyloxy)methyl]-2,3-dihydropyridine by the action of potassium tert-butoxide in DMSO afforded a mixture of 2-(methylsulfanyl)-6-[(vinyloxy)methyl]- pyridine and 3-methoxy-6-methyl-2-(methylsulfanyl)pyridine at a ratio of 48: 52. [ABSTRACT FROM AUTHOR]