학술논문
Rhodium supported on tetragonal or monoclinic ZrO2 as catalyst for the partial oxidation of methane.
Document Type
Article
Source
Subject
*RHODIUM catalysts
*ZIRCONIUM oxide
*PARTIAL oxidation
*METHANE
*OXIDATION
*CATALYTIC activity
*METAL catalysts
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Language
ISSN
0926-3373
Abstract
Highlights: [•] Rh/ZrO2 as catalysts for the catalytic partial oxidation of methane (CPO). [•] A role of the ZrO2 support, tetragonal (t-ZrO2) or monoclinic (m-ZrO2), emerges. [•] Rh/t-ZrO2 catalysts are far more active and selective than Rh/m-ZrO2 ones. [•] The interaction of Rh species with the support is stronger on t-ZrO2 than m-ZrO2. [•] Rh species are more dispersed on t-ZrO2 than m-ZrO2. [ABSTRACT FROM AUTHOR]