학술논문
Diverse Hydrogen-Bonded Structural Motifs in 1,4-Diazabicyclo[2.2.2]octane N,N'-Dioxide Salts with Oxoanions.
Document Type
Article
Source
Subject
*SALTS
*INFRARED spectroscopy
*HYDROGEN bonding
*X-ray diffraction
*PROTON transfer reactions
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Language
ISSN
1422-8599
Abstract
Four new hybrid inorganic–organic salts of 1,4-diazabicyclo[2.2.2]octane N,N'-dioxide (odabco) with the formulae odabco·2HNO3 (1), odabco·HClO4 (2), odabco·H2SO4 (3) and odabco·2H2SO4 (4) were synthesized and characterized by single-crystal x-ray diffraction (XRD), powder XRD and infrared spectroscopy. Compound 1 is based on the isolated (H2odabco)2+ fragments, representing 0D structure. 2 is based on cationic 1D {Hodabco}nn+ hydrogen-bonded chains. Compound 3 comprising a strongly coordinated sulfate anion consists of two-component hydrogen-bonded {-H2odabco-SO4−} fragments forming uncharged 1D helical chains. 4 contains both {-HSO4-}nn– and {-HSO4-H2odabco-HSO4−} hydrogen bonding motifs, resulting in a 3D polymeric network. A comparative structural analysis of both the obtained and the previously reported cognate structures was performed to rationalize the impact of the degree of odabco protonation and the anion donor ability on the structural features and dimensionalities of odabco-based hydrogen-bonded lattices. [ABSTRACT FROM AUTHOR]