학술논문
Controlling the Photofunctionality of a Polyanionic Heteroleptic Copper(I) Photosensitizer for CO2 Reduction Using Its Ion‐pair Formation with Polycationic Ammonium in Aqueous Media.
Document Type
Article
Author
Source
Subject
*PHOTOSENSITIZERS
*COPPER
*AMMONIUM
*IONIC interactions
*TRP channels
*SULFONATES
*RADIATIVE transfer equation
*
*
*
*
*
*
Language
ISSN
0044-8249
Abstract
A water‐soluble trianionic heteroleptic copper(I) photosensitizer having four sulfonate groups (CuPS3−) was found to afford the 1 : 2 ion‐pair adduct with dicationic alkylammonium (hexamethonium) cations (HM2+) in aqueous media, leading to exhibit excellent photophysical and photocatalytic performances owing to the substantial suppression of water‐derived non‐radiative decay of the photoexcited state. [ABSTRACT FROM AUTHOR]