학술논문
Gold‐Catalyzed Synthesis of π‐Extended Carbazole‐Based Systems and their Application as Organic Semiconductors.
Document Type
Article
Author
Source
Subject
*VACUUM deposition
*ORGANIC semiconductors
*THIN film transistors
*TRANSISTORS
*OPTICAL properties
*HOMOGENEOUS catalysis
*CARBAZOLE
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Language
ISSN
1615-4150
Abstract
Herein we describe a gold‐catalyzed bidirectional synthesis of N‐heteropolycyclic compounds bearing carbazole moieties – namely π‐extended benzodicarbazoles and π‐extended indolocarbazoles. Overall, four previously unknown core structures were synthesized. This approach is convergent, modular and the gold‐catalyzed key step comprises of a cascade reaction starting from stable di‐azido compounds. The obtained molecules were fully characterized and their optical and electronic properties as well as their performance in organic thin‐film transistors generated by vacuum deposition were studied. Charge‐carrier mobilities of up to 0.3 cm2/Vs were measured. [ABSTRACT FROM AUTHOR]