학술논문

Recent Advances in the Electrochemical α‐C–H Bond Functionalization of Carbonyl Compounds.
Document Type
Article
Source
Advanced Synthesis & Catalysis. 11/16/2018, Vol. 360 Issue 22, p4266-4292. 27p.
Subject
*CARBONYL compounds
*CHEMICAL bonds
*ORGANIC chemistry
*BOND formation mechanism
*ELECTROCHEMICAL analysis
*AMIODARONE
Language
ISSN
1615-4150
Abstract
The α‐C–H functionalization of carbonyl compounds represents a cornerstone of organic chemistry. Site‐selective α‐C−H bond functionalization of carbonyl compounds to afford more versatile functionalized groups has become a promising strategy for atom‐economical C−C and C−X bond formation. Organic electrosynthesis is revolutionizing the nature of organic synthesis, and this field has seen explosive growth in recent years. In this review, we discuss advances in the use of electrochemistry for the α‐C–H oxidative functionalization of carbonyl compounds published since 2000. [ABSTRACT FROM AUTHOR]