학술논문

Photocatalytic Degradation of 2,4-Dichlorophenol in Water Using MgAl Activated Hydrotalcites as Photocatalyst.
Document Type
Article
Source
Topics in Catalysis. Sep2022, Vol. 65 Issue 13-16, p1469-1481. 13p.
Subject
*PHOTODEGRADATION
*WATER use
*LAYERED double hydroxides
*HYDROXYL group
*ORGANIC compounds
Language
ISSN
1022-5528
Abstract
2,4-Dichlorophenol (2,4-DCP) is a persistent organic compound present in many water reservoirs for human consumption, generating a high risk for all species, especially for humans due to its toxicity. In this work, Mg/Al = 2, 3 and 4 layered double hydroxides activated at 450 °C are presented for the formation of photocatalysts formed by the mixture of MgO–MgAl2O4 oxides for the photocatalytic degradation of 2,4-DCP in aqueous solution in a UV irradiated reaction system. The results showed a good photocatalytic activity by achieving a complete degradation of 2,4-DCP up to mineralization. The high degradation capacity of 2,4-DCP is attributed to the presence of holes in these materials that promote the formation of hydroxyl radicals (OH⋅) and superoxide radicals (O2⋅−) in only 30 min of reaction time. [ABSTRACT FROM AUTHOR]