학술논문

Effect of unintentional nitrogen incorporation on n-type doping of β-Ga2O3 grown by molecular beam epitaxy.
Document Type
Article
Source
CrystEngComm. 1/14/2022, Vol. 24 Issue 2, p269-274. 6p.
Subject
*MOLECULAR beam epitaxy
*GALLIUM nitride films
*N-type semiconductors
*QUARTZ
*BORON nitride
*NITROGEN
*PLASMA sources
Language
ISSN
1466-8033
Abstract
The effect of unintentional nitrogen incorporation on n-type doping of β-Ga2O3 films grown by plasma-assisted molecular beam epitaxy was demonstrated. Nitrogen atoms, at a concentration as high as 2 × 1019 cm−3, were confirmed to originate from the decomposition of a pyrolytic boron nitride (PBN) crucible in the plasma source. These atoms acted as acceptors in β-Ga2O3 and severely compensate Si donors, thereby hindering the generation of n-type β-Ga2O3. Instead, a quartz (SiO2) crucible free of nitrogen atoms could overcome this problem, and led to generation of n-type β-Ga2O3 with a tunable electron concentration of 5.0 × 1016 to 2.6 × 1019 cm−3. [ABSTRACT FROM AUTHOR]