학술논문

Spodium bonding in bis(alkynyl)mecurials.
Document Type
Article
Source
Chemical Communications. 3/4/2024, Vol. 60 Issue 18, p2552-2555. 4p.
Subject
*BORATES
*FLUORIDES
*MERCURY
Language
ISSN
1359-7345
Abstract
The new bis(alkynyl)mercurial Hg{C≡CSeC≡W(CO)2(Tp*)}2 (Tp* = tris(dimethylpyrazolyl)borate) forms adducts with fluoride and phenathroline, the structures of which are interpreted in the context of two-coordinate mercury presenting a σ-torroid for spodium bonding. [ABSTRACT FROM AUTHOR]