학술논문

Localized Normalization for Improved Calibration Curves of Manganese and Zinc in Laser-Induced Plasma Spectroscopy.
Document Type
Article
Source
AIP Conference Proceedings. 2017, Vol. 1824 Issue 1, p1-8. 8p. 1 Color Photograph, 6 Graphs.
Subject
*LASER-induced breakdown spectroscopy
*MANGANESE
*ZINC
*POTASSIUM bromide
*PLASMA gases
Language
ISSN
0094-243X
Abstract
Laser-induced plasma spectroscopy is performed to determine the elemental compositions of manganese and zinc in potassium bromide (KBr) matrix. This work has utilized Q-switched Nd:YAG laser installed in LIBS2500plus system at fundamental wavelength. The pelletized sample were ablated in air with maximum laser energy of 650 mJ for different gate delays ranging from 0-18 μs. The spectra of samples are obtained for five different compositions containing preferred spectral lines. The intensity of spectral line is observed at its maximum at a gate-delay 0.83 μs and subsequently decayed exponentially with the increasing of gate delay. Maximum signal-to--background ratio of Mn and Zn were found at gate delays of 7.92 and 7.50 μs, respectively. Initial calibration curves show bad data fitting, whereas the locally normalized intensity for both spectral lines shows enhancement since it is more linearly regressed. This study will give a better understanding in studying the plasma emission and the spectra analysis. [ABSTRACT FROM AUTHOR]