학술논문
Molecular-field splitting of the 2p[sub 3/2] peak in x-ray photoelectron spectra of second-row...
Document Type
Article
Author
Source
Subject
*PHOTOELECTRON spectroscopy
*ATOMIC spectra
*VALENCE (Chemistry)
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Language
ISSN
0021-9606
Abstract
Examines the theory of molecular-field induced splitting of the 2p[sub 3/2] peak in x-ray photoelectron spectra of second-row atoms using PH[sub] and PF[sub 3] examples. Amplification of the molecular-field splitting; Analysis based on second-order Moller-Plesset theory; Extension of the pseudoatomic valence theory.