부산대학교 도서관

Reservoir quality of sandstones can be controlled by the dissolution of minerals such as K‐feldspar. The present work investigates the impact of dissolution of K‐feldspar (Orthoclase) on the resulting porosity and permeability of sandstones using a thermodynamically consistent multiphase‐field model. Two novel aspects of this research are: (a) identification and calibration of interfacial surface energy and kinetics related model parameters based on existing literature, to account for the formation and growth of diamond‐shaped etch‐pits during dissolution, and (b) the workflow for three‐dimensional modeling of dissolution at sub‐micrometer scale within individual feldspar grains, followed by up‐scaling the phenomenon to a multigrain pack analogous to sandstone. The simulated dissolution, when visualized in the relevant planes, show clear similarities with microphotographs of natural samples and previous numerical works, in terms of facet‐formation and merging of the etch‐pit morphologies. For the computation of permeability, computational fluid dynamics analysis was performed for grain packs at different stages of dissolution. Finally, the generated data‐sets were analyzed to study the impact of rock properties including a fraction of feldspar grains and their crystallographic orientation on the porosity, permeability and their correlations, for sandstones undergoing K‐feldspar dissolution. At the same porosity, sandstones containing a greater proportion of K‐feldspar grains are expected to have greater permeabilities. The devised workflow for model calibration and up‐scaling complimented by the innovative post‐processing and visualization techniques can be adapted to study dissolution of other minerals in different rocks. Plain Language Summary: The dissolution of minerals like K‐feldspar controls how well sandstones act as a storage sites for fluids. In this work, we use a multi‐physics modeling approach and perform simulations to study how K‐feldspar grain dissolution impacts the overall porous and permeable characteristics of natural sandstones. The calibration of a simulation model helped us to capture the shape and growth characteristics of etch‐pits, which are responsible for the dissolution of K‐feldspar grains. Additionally, we perform pre‐ and post‐processing techniques which allow the up‐scaling of this phenomenon to a multigrain pack analogous to sandstone, while also reducing the computational costs. When comparing the simulation result with natural samples, the etch‐pit's morphology evolution showcases great resemblance. Furthermore, for computation of the permeability evolution during K‐feldspar grain dissolution, we performed computational fluid dynamics analysis. The fluid‐flow analysis allows us to analyze the effect of the volume of K‐feldspar grains and their respective cleavage plane (weaker plane, where etch‐pits form) orientations on the overall porosity‐permeability evolution within the sandstone. This work showcases new modeling techniques, which can be used in future work, for handling large‐scale dissolution processes with different minerals and rock types. Key Points: A phase‐field investigation illuminating the etch‐pitting behavior on the surface of K‐feldspar and its impact on reservoir qualityA novel simulation‐based workflow for capturing the etch‐pitting phenomena in sandstone up to three orders of magnitude largerOrientation of etch‐pits and volume percentage of K‐feldspar substantially affect porosity‐permeability correlation in sandstone [ABSTRACT FROM AUTHOR]