학술논문

New age chloride shielding strategies for corrosion resistant direct seawater splitting.
Document Type
Article
Source
Chemical Communications. 4/22/2023, Vol. 59 Issue 31, p4578-4599. 22p.
Subject
*SEAWATER
*HYDROGEN as fuel
*CORROSION engineering
*ENERGY consumption
*CHLORIDES
Language
ISSN
1359-7345
Abstract
Electrocatalytic direct seawater splitting is considered to be one of the most desirable and necessary approach to produce substantial amount of green hydrogen to meet the energy demand. However, practical seawater splitting remains far-fetched due to the electrochemical interference of multiple elements present in seawater, among which chlorine chemistry is the most aggravating one, causing severe damages to electrodes. To overcome such limitations, apart from robust electrocatalyst design, electrolyte engineering along with in depth corrosion engineering are essential aspects, which needs to be thoroughly judged and explored. Indeed, extensive studies and various approaches including smart electrolyzer design have been attempted in the last couple of years on this matter. The present review offers a comprehensive discussion on various strategies to achieve effective and sustainable direct seawater splitting, avoiding chlorine electrochemistry to achieve industry-level performances. [ABSTRACT FROM AUTHOR]