학술논문
Investigation of H-Complex Formation of Derivatives of Naphthalimide with Phenol by IR Spectroscopy.
Document Type
Article
Source
Subject
*IMIDES
*SPECTRUM analysis
*INFRARED spectroscopy
*CARBONYL compounds
*HETEROCYCLIC chemistry
*STERIC hindrance
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Language
ISSN
0009-3122
Abstract
The H-complex-forming reaction of naphthalimide derivatives with phenol has been investigated by JR spectroscopy. Jt was shown that for the majority of compounds studied the carbonyl group is the main center of basicity. In the case of amino-substituted imides of naphthalic acid transfer is possible of the reaction center from the carbonyl group to the nitrogen atom of the substituent introduced into the naphthalene ring However because of steric hindrance this occurs only for amino- and methylamino- substituted naphthalimide. [ABSTRACT FROM AUTHOR]