학술논문

Mechanical and Thermal Properties of All-Wood Biocomposites through Controllable Dissolution of Cellulose with Ionic Liquid.
Document Type
Article
Source
Polymers (20734360). Feb2020, Vol. 12 Issue 2, p361. 1p. 3 Diagrams, 2 Charts, 7 Graphs.
Subject
*THERMAL properties
*IONIC liquids
*CELLULOSE
*SCANNING electron microscopes
*TIME pressure
*NONAQUEOUS phase liquids
*WOOD preservatives
Language
ISSN
2073-4360
Abstract
All-wood biocomposites were prepared with an efficient method. The ionic liquid of 1-butyl-3-methylimidazolium chloride (BMIMCl) was used to impregnate manchurian ash (MA) before hot-pressing, and the all-wood biocomposites were prepared by controllable dissolving and regenerating the cellulose in MA. The Fourier transform infrared analysis suggested that all the components of MA remained unchanged during the preparation. X-ray diffraction, thermogravimetric and scanning electron microscope analysis were carried out to study the process parameters of hot-pressing pressure and time on the crystallinity, thermal properties and microstructure of the all-wood biocomposites. The tensile strength of the prepared all-wood biocomposites reached its highest at 212.6 MPa and was increased by 239% compared with that of the original MA sample. The thermogravimetric analysis indicated that as the thermo-stability of the all-wood biocomposites increased, the mass of the residual carbon increased from 19.7% to 22.7% under a hot-pressing pressure of 10 MPa. This work provides a simple and promising pathway for the industrial application of high-performance and environmentally friendly all-wood biocomposites. [ABSTRACT FROM AUTHOR]