학술논문
Crystal structure of a methyl benzoate quadruple-bonded dimolybdenum complex.
Document Type
Article
Author
Source
Subject
*CRYSTAL structure
*METHYL benzoate
*CHEMICAL bond lengths
*SPACE groups
*MOLYBDENUM
*LIGANDS (Chemistry)
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Language
ISSN
2056-9890
Abstract
Quadruple-bond dimolybdenum complexes provide invaluable insight into the two-electron bond, with structural chemistry providing a foundation for examination of bond properties. The synthesis and solid-state structure of the quadruple-bonded dimolybdenum(II) complex tetrakis(μ-4-methylbenzoato-κ²O:O′)bis[(tetrahydrofuran-κO)molybdenum(II)] tetrahydrofuran disolvate, [Mo2(C8H7O2)4(C4H8O)2]·2C4H8O, are presented. This complex crystallizes in a triclinic cell with low-symmetry space group P[\overline{1}]. The dimolybdenum paddlewheel structure comprises four methylbenzoate ligands and two axial THF ligands. The dimolybdenum bond distance of 2.1012 (4) Å is exemplary of this class of compounds. [ABSTRACT FROM AUTHOR]