학술논문
Mechanochemically-generated solid state complex of C60 -fullerene with tetra-(5,7-diphenyl)calix[4]azulene, NMR, XRD and DFT studies.
Document Type
Article
Author
Source
Subject
*SOLID state chemistry
*MOLECULAR structure of fullerenes
*DENSITY functional theory
*SUPRAMOLECULAR chemistry
*GAS phase reactions
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Language
ISSN
1061-0278
Abstract
The synthesis of tetra-(5,7-diphenyl)calix[4]azulene via the reaction of 5,7-diphenylazulene with formaldehyde is described. Its solid-state supramolecular complexation with C60 produced by a grinding of the two components was evaluated by solid-state 13C-NMR spectroscopy and X-ray powder diffraction. Gas-phase DFT studies of possible structures are reported. [ABSTRACT FROM AUTHOR]