학술논문
Dissipative sequential catalysis via six-component machinery.
Document Type
Article
Source
Subject
*CATALYSIS
*COPPER
*FUEL systems
*MACHINERY
*PYRROLIDINE
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Language
ISSN
1359-7345
Abstract
Triphenyl phosphane (TPP) and an epoxide as a fuel system transiently transformed a non-catalytic six-component turnstile into a four-component catalytic rotor releasing N-methyl pyrrolidine and a copper(I) complex. The two latter compounds acted synergistically as catalysts to perform first a Michael addition and then a 5-exo-dig cyclization, giving rise to dissipative sequential catalysis. [ABSTRACT FROM AUTHOR]