학술논문
Hydrolysis of a carbamate triggered by coordination of metal ions.
Document Type
Article
Author
Source
Subject
*METAL ions
*HYDROLYSIS
*COPPER chlorides
*METAL chlorides
*COPPER
*CARBON dioxide
*SELF-immolation
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Language
ISSN
1477-9226
Abstract
The mechanism of carbamate activation promoted by different metal ions has been explored in this work. The reaction of the carbamate ligand H2L with chloride metal salts (M = Ni, Cu, Zn, Cd) leads to the coordination of the metal ions to the ligand, causing hydrolysis of the systems. This self-immolation process results in mononuclear dihydrazone complexes, carbon dioxide and the release of alcohol species from the pendant groups of the carbamate ligand. The conditions under which this process occurs have been studied in detail. [ABSTRACT FROM AUTHOR]