학술논문
Breakthrough in the α-Perchlorination of Acyl Chlorides.
Document Type
Article
Author
Source
Subject
*ACYL chlorides
*HALOGENATION
*CHLORINE
*CATALYSIS
*CHLORIDES
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*
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Language
ISSN
0039-7881
Abstract
The preparation of α-perchloroacyl chlorides, from reaction of the corresponding unfunctionalized acyl halides with chlorine, was efficiently achieved under base-catalysis, using a tetraalkylammonium chloride as catalyst. The process is solvent-free and the procedure is easy, inexpensive, and suitable for scale-up. [ABSTRACT FROM AUTHOR]