학술논문
Radical reactions of tricyclo[4.1.0.0]heptane and 1-phenyltricyclo[4.1.0.0]heptane with trifluoromethyl (phenylethynyl) sulfone.
Document Type
Article
Author
Source
Subject
*TRIFLUOROMETHYL compounds
*HEPTANE
*FREE radical reactions
*FREE radicals
*CARBON-carbon bonds
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Language
ISSN
1070-4280
Abstract
The article focuses on findings of a study on radical reactions of tricyclo[4.1.0.02]heptane and 1-Phenyltricyclo[4.1.0.0]heptane with trifluoromethyl (Phenylethynyl) Sulfone. Topics include interaction of tricycloheptanes with trifluoromethyl phenylethynyl sulfone, or triflone, under photochemical and thermal initiation; reaction of triflone with tricycloheptanes under conditions of radical initiation; and formation of norpinane products to the opening of the central carbon-carbon bond.