학술논문
Reductive Deuteration of Acyl Chlorides for the Synthesis of α , α -Dideuterio Alcohols Using SmI 2 and D 2 O.
Document Type
Article
Author
Source
Subject
*ACYL chlorides
*DEUTERATION
*ALCOHOL drinking
*CHARGE exchange
*DEUTERIUM
*FUNCTIONAL groups
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Language
ISSN
1420-3049
Abstract
The synthesis of α,α-dideuterio alcohols has been achieved via single electron transfer reductive deuteration of acyl chlorides using SmI2 and D2O. This method is distinguished by its remarkable functional group tolerance and exquisite deuterium incorporation, which has also been applied to the synthesis of valuable deuterated agrochemicals and their building blocks. [ABSTRACT FROM AUTHOR]