학술논문
Bis(acetylacetonato-κ2 O, O′)[2,2′-methylenebis(4,6-xylenolato)-κ2 O, O′]titanium(IV).
Document Type
Article
Source
Subject
*COORDINATION compounds
*SODIUM acetate
*TITANIUM
*LIGANDS (Chemistry)
*MOLECULAR association
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Language
ISSN
1600-5368
Abstract
The title compound, [Ti(C5H7O2)2(C17H18O2)], was synthesized by the reaction of Ti(acac)2Cl2 (acac = acetylacetonate) with one equivalent of the diol {[HOC6H2(Me)2](μ-CH2)[(Me)2C6H2OH]} in the presence of sodium acetate. The coordination about the Ti atom is slightly distorted octahedral and the bisphenoxo ligand adopts an `open book' conformation. [ABSTRACT FROM AUTHOR]