학술논문
Functionalized Phosphines: Synthesis, Reactivity and Transition Metal Chemistry.
Document Type
Article
Source
Subject
*PHOSPHINE
*TRANSITION metals
*ETHERS
*HETEROCYCLIC compounds
*INORGANIC compounds
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Language
ISSN
1042-6507
Abstract
Ten-membered heterocycles of the type PhN(PCl 2 ){OC 6 H 2 (R) 2 (μ-S-(CH 2 ))((R) 2 --C 6 H 2 O--)} (R = Me, i Pr or t Bu) have been prepared and their transition metal chemistry is explored. Functionalised phosphines react with transition metals to give interesting metallacycles. Several Group 6, ruthenium, platinum metals and novel titanium(IV) metallacycles have been structurally characterized. [ABSTRACT FROM AUTHOR]