학술논문
Neodymium Complex with a Scorpionate Phosphoryl Pyridyl Ligand: Structure in Crystal and in Solution.
Document Type
Article
Author
Source
Subject
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ISSN
1070-3632
Abstract
The coordination properties of the scorpionate ligand 2-PyCH[P(O)Ph2]2 were studied using complexation with neodymium nitrate as an example. The molecular structure of the [Nd{(2-PyCH[P(O)Ph2]2}(NO3)3(H2O)] complex was determined by X-ray diffraction analysis. The structures of the ligand and the complex were studied in the solid state and in solutions by vibrational and multinuclear (1H, 13C, 31P) NMR spectroscopy. The tridentate O,O,N-coordination of the ligand found in the crystal is retained in solution. [ABSTRACT FROM AUTHOR]