학술논문

Morphological instability of Ag films caused by phase transition in the underlying Ta barrier layer.
Document Type
Article
Source
Applied Physics Letters. 8/18/2014, Vol. 105 Issue 7, p1-6. 6p. 3 Black and White Photographs, 3 Graphs.
Subject
*METAL coating
*SILVER
*MORPHOLOGY
*PHASE transitions
*TANTALUM
*HIGH temperature electronics
Language
ISSN
0003-6951
Abstract
Wide-bandgap (WBG) semiconductor technologies are maturing and may provide increased device performance in many fields of applications, such as high-temperature electronics. However, there are still issues regarding the stability and reliability of WBG devices. Of particular importance is the high-temperature stability of interconnects for electronic systems based on WBGsemiconductors. For metallization without proper encapsulation, morphological degradation can occur at elevated temperatures. Sandwiching Ag films between Ta and/or TaN layers in this study is found to be electrically and morphologically stabilize the Ag metallization up to 800 °C, compared to 600 °C for uncapped films. However, the barrier layer plays a key role and TaN is found to be superior to Ta, resulting in the best achieved stability, whereas the difference between Ta and TaN caps is negligible. The α-to-β phase transition in the underlying Ta barrier layer is identified as the major cause responsible for the morphological instability observed above 600 &3176;C. It is shown that this phase transition can be avoided using a stacked Ta/TaN barrier. [ABSTRACT FROM AUTHOR]