학술논문

Synthesis of 1,2,4,5-oxadiazaboroles by three-component condensations of hydroxylamines, nitriles, and diarylborinic acids.
Document Type
Article
Source
Canadian Journal of Chemistry. 2023, Vol. 101 Issue 3, p205-211. 7p.
Subject
Language
ISSN
0008-4042
Abstract
A method for the synthesis of substituted 1,2,4,5-oxadiazaboroles is described, in which hydroxylamines, nitriles, and diarylborinic acids engage in a three-component condensation reaction. The protocol provides access to a substitution pattern that is not readily available through other methods—namely, 2,3-disubstitution, with a tetracoordinate boron center. Structures of representative members of this class of heterocycles were determined by single crystal X-ray diffraction analysis. [ABSTRACT FROM AUTHOR]