학술논문
On-surface synthesis of metal-organic frameworks: the critical role of the reaction conditions.
Document Type
Article
Author
Source
Subject
*METAL-organic frameworks
*HONEYCOMB structures
*CHEMICAL species
*COPPER
*ADATOMS
*THERMODYNAMICS
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Language
ISSN
1359-7345
Abstract
Two different metal-organic frameworks with either a honeycomb or Kagome structure were grown on Cu(111) using para-aminophenol molecules and native surface adatoms. Although both frameworks are made up from the same chemical species, they are structurally different emphasizing the critical role being played by the reaction conditions during their growth. This work highlights the importance of the balance between thermodynamics and kinetics in the final structure of surface-supported metal-organic networks. [ABSTRACT FROM AUTHOR]