학술논문

Enhanced energy storage performance of KNN-BLZS dielectric ceramic.
Document Type
Article
Source
Applied Physics A: Materials Science & Processing. Jul2023, Vol. 129 Issue 7, p1-9. 9p.
Subject
*ENERGY storage
*LEAD-free ceramics
*DIELECTRICS
*RAMAN spectroscopy
*CRYSTAL growth
*CERAMICS
Language
ISSN
0947-8396
Abstract
Exploring high-performance energy storage dielectric ceramics for pulse power applications is paramount concern for a multitude of researchers. In this work, a (1 – x)K0.5Na0.5NbO3-xBi0.5La0.5(Zn0.5Sn0.5)O3 ((1–x)KNN-xBLZS) lead-free relaxor ceramic was successfully synthesized by a conventional solid-reaction method. X-ray diffraction and Raman spectra confirm the perovskite structure of the ceramics. With the addition of BLZS, the crystal growth is suppressed, the ceramic resistivity increases, and the relaxation properties of ceramics are enhanced. By optimizing the composition to x = 0.12, we achieved a significant ΔP of 12.8 μC/cm2, a Pmax of 14.6 μC/cm2, and a Pr of 1.8 μC/cm2. The resulting Wrec reached 0.84 J/cm3, accompanied by an outstanding efficiency (η) of 76%, superior frequency reliability, and robust thermal stability. Owing to these exceptional properties, the 0.88 KNN-0.12 BLZS ceramic demonstrates great potential for pulse power applications. [ABSTRACT FROM AUTHOR]