학술논문
Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas.
Document Type
Article
Author
Source
Subject
*DECARBOXYLATION
*UREA
*
Language
ISSN
1420-3049
Abstract
A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N–C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system's ppm Fe. [ABSTRACT FROM AUTHOR]