학술논문

Nature-inspired catalytic asymmetric rearrangement of cyclopropylcarbinyl cation.
Document Type
Article
Source
Science Advances. 5/12/2023, Vol. 9 Issue 19, p1-12. 12p.
Subject
*SARS-CoV-2
*LIQUID chromatography-mass spectrometry
Language
ISSN
2375-2548
Abstract
The article presents a study which reported a small molecule-catalyzed asymmetric rearrangement of cyclopropylcarbinyl cations, leading to a series of chiral homoallylic sulfide products with good to excellent yields and enantioselectivities. Topics discussed include reaction development and optimization, screening of substrate scopes, and mechanistic consideration.