학술논문
An x-ray diffraction study of the reaction products of copper(II) chloride with N,N-bis(5-methylpyridin-2-yl)oxalamide.
Document Type
Article
Source
Subject
*X-ray diffraction
*CHEMICAL reactions
*COPPER compounds
*METAL complexes
*CHLORIDES
*HYDROLYSIS
*AMIDES
*COORDINATION polymers
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Language
ISSN
0022-4766
Abstract
Polymeric complexes of [CuClL] copper(I) chloride ( 1) (L = N,N-bis(5-methylpyridin-2-yl)-oxalamide)) and {[Cu(CO)ClL](L)·2HO} copper(II) chloride ( 2) are obtained. The complexes are studied by powder and single crystal XRD. It is found that during the reaction of L with copper(II) chloride in the formation of complex 1 copper(II) is reduced to copper(I), while the formation of complex 2 is accompanied by the hydrolysis of the ligand. [ABSTRACT FROM AUTHOR]