학술논문
Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2- tert-butyltetrazol-5-yl)pyridine.
Document Type
Article
Author
Source
Subject
*MAGNETIC properties
*CHEMICAL synthesis
*ISOTHIOCYANATES
*IRON
*SINGLE crystals
*X-ray diffraction
*
*
*
*
*
Language
ISSN
0022-4766
Abstract
Iron(II) dicyanamide and isothiocyanate compounds with 2-(2- tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL(CN)]•2HO ( I) and [FeL(NCS)]HO ( II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μ( Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K. [ABSTRACT FROM AUTHOR]