학술논문
A perylene complex with a one-dimensional coordination polymer containing [Mn6 O2 (CHCl2 COO)10 (H2 O)2 ] cluster units linked by 3,10-perylenequinone bridges.
Document Type
Article
Author
Source
Subject
*PERYLENE
*SINGLE molecule magnets
*COORDINATE covalent bond
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Language
ISSN
1144-0546
Abstract
The crystals of a perylene complex with the polymeric cluster containing [Mn6O2(O2CCHCl2)10(H2O)2] units assembled by 3,10-perylenequinone bridges, {[Mn6O2(O2CCHCl2)10(H2O)2(C20H10O2)]2n·(C20H12)n} (I), were obtained in the reaction of [Mn12O12(O2CCHCl2)16(H2O)4] with perylene. Unlike the Mn12 oxodichloroacetate cluster, the reaction of the Mn12 oxobenzoate cluster, [Mn12O12(O2CPh)16(H2O)4], with perylene does not occur. However, it turned out that the crystals isolated from the reaction are a new Mn12 oxobenzoate cluster containing three molecules of coordinated H2O and solvate molecules of hexane, [Mn12O12(O2CC6H5)16(H2O)3]·2C6H12 (II). Crystal structures of complexes I and II as well as the magnetic properties of the former were studied. [ABSTRACT FROM AUTHOR]