학술논문

AgS-AsS-TlI chalcogenide glasses as perspective material for solid-state chemical sensors.
Document Type
Article
Source
Russian Journal of Applied Chemistry. Aug2014, Vol. 87 Issue 8, p1044-1048. 5p.
Subject
*CHALCOGENIDES synthesis
*SOLID state chemistry
*CHEMICAL detectors
*RADIOISOTOPES
*BIOLOGICAL transport
*ELECTRIC conductivity
Language
ISSN
1070-4272
Abstract
Modern research techniques with radioactive isotopes were used to study the transport characteristics, (conductivity and diffusion) in chalcogenide membrane materials of the AgS-AsS-TlI system. It was demonstrated that, on raising the silver sulfide concentration in a glass, the total electrical conductivity grows by two orders of magnitude, which is due to the pronounced change of the band structure and to the increase in the electronic component of the conductivity. New chemical sensors for determination Tl ions in solutions were developed on the basis of these solid-state studies. [ABSTRACT FROM AUTHOR]