학술논문
Synthesis and Structures of Fused N-Heterocylic Carbenes and Their Rhodium Complexes.
Document Type
Article
Author
Source
Subject
*METAL complexes
*ORGANORHODIUM compounds
*MOLECULAR structure
*COMPLEX compounds synthesis
*HETEROCYCLIC compounds
*CARBENES
*METATHESIS reactions
*LIGANDS (Chemistry)
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Language
ISSN
0276-7333
Abstract
New procedures for the synthesis of N-heterocyclic carbenes with multiple fused rings have been developed utilizing a key ring-closing metathesis step. Rhodium complexes were obtained via the pentafluorophenyl carbene adducts. Solid-state structural behaviors of the new carbene ligands were analyzed via X-ray crystallography. [ABSTRACT FROM AUTHOR]