학술논문
Electrochemically Induced Phosphorus–Methyl Bond Formation Involving the Complex [Co(Ph2 PCH2 P(Ph)2 PPPPP(Ph)2 CH2 PPh2 )]BF4 .
Document Type
Article
Author
Source
Subject
*CYCLIC voltammetry
*PHOSPHONIUM compounds
*METHYL iodide
*METHYLATION
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Language
ISSN
1023-1935
Abstract
The electrochemical properties of [Co(Ph2PCH2P(Ph)2PPPPP(Ph)2CH2PPh2)]BF4 complex have been studied by the method of cyclic voltammetry. The electrochemical methylation of this complex have been cunducted in the presence of iodomethane which has led to the formation of phosphonium salt—methylene bis(methyldiphenylphosphonium) diiodide as final product. It was found, that this reaction proceeds with the breakage of the P–P bonds in polyphosphorus ligand and with the formation of new P–C bonds. [ABSTRACT FROM AUTHOR]