학술논문

Synthesis of bicyclic diesters of malonic and succinic acids.
Document Type
Article
Source
Russian Journal of General Chemistry. Jan2017, Vol. 87 Issue 1, p13-15. 3p. 1 Diagram, 3 Charts, 1 Graph.
Subject
*CHEMICAL synthesis
*ESTERS
*SUCCINIC acid
*MALONIC acid
*ESTERIFICATION
*DICARBOXYLIC acids
*CATALYTIC activity
Language
ISSN
1070-3632
Abstract
Monoesters of malonic and succinic acids have been prepared in high yields by the BF·OEt-catalyzed addition of the acids to bicyclo[2.2.1]hept-2-ene. The synthesized monoesters were introduced in the reaction of esterification with saturated monoatomic alcohols С-С in the presence of the KU-2-8 catalyst in the H-form, and the corresponding mixed diesters of dicarboxylic acids were obtained in high yields. [ABSTRACT FROM AUTHOR]