학술논문
The First Seven-Coordinated Triiodo Complex of Rhenium(III).
Document Type
Article
Author
Source
Subject
*LIGANDS (Chemistry)
*RHENIUM
*METAL ions
*BUTYL group
*MANGANESE group
*COMPLEX compounds
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Language
ISSN
1063-7745
Abstract
The reaction of cis-[ReO2I(PPh3)2] with tert-butyl isocyanide in benzene led to the isolation of the complex [ReI3(CN-t-Bu)3(PPh3)] (1). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with tert-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion. [ABSTRACT FROM AUTHOR]