부산대학교 도서관

To understand the mechanistic pathway of arsenic (As) enrichment and mobilization in groundwater (southeastern Bangladesh) and to evaluate the water quality as well as associated health risks, a suite of systematically collected groundwater samples (depth: 17–61 m) were analyzed. Arsenic concentrations (μg L−1) in the groundwater samples were ranged from 6 to 581 with a mean value of 199 which is significantly higher than the recommended values. The assessment of water quality using entropy water quality index and irrigation water quality indices revealed that the groundwater in the studied region was not recommended for drinking and irrigation, respectively with few exceptions. Dominant water types in the studied area were Ca–Mg–HCO 3, Na–HCO 3 , and Na–Cl types. Various forms of water-rock interactions, leaching of evaporates, and the confined nature of the aquifer mostly control the hydro-chemical parameters. Fe/Mn bound As are likely to be released in the aquifer through the dissolution of carbonate minerals of Fe/Mn while the higher degree of water-rock interaction and probable oxidation of organic materials helped to elevate As concentration. The probable longer residence time of groundwater guided by topographic slope and the neighboring clayey aquitard govern the As mobilization in the aquifer. Probabilistic health risk assessment revealed that groundwaters from the studied area can cause both non-carcinogenic and carcinogenic health risks. [Display omitted] • Arsenic (As) concentrations in groundwater are much higher than WHO guidelines. • Fe/Mn bound As is released in the aquifer through water-rock interactions. • Topographic slope and clayey aquitard govern the As enrichment in the aquifer. • Water quality and health risk assessment revealed the unsuitability of groundwater. [ABSTRACT FROM AUTHOR]