학술논문

Solvent-free and ionic liquid catalysed three-component method synthesis of spiro-2-amino-4H-pyrans derivatives.
Document Type
Article
Source
Journal of Chemical Research. Nov2012, Vol. 36 Issue 11, p638-640. 3p. 4 Diagrams, 1 Chart.
Subject
*IONIC liquids
*PYRAN derivatives
*CHEMICAL synthesis
*CATALYSIS
*SALTS
*FLUIDS
Language
ISSN
1747-5198
Abstract
In the absence of any solvent, a series of spiro-2-amino-4H-pyrans derivatives were synthesised via the three component reaction of malononitrile and α-methylencarbonyl compounds/enol with 9,10-phenanthroquinone or acenaphthenequinone using 1-butyl-3-methylimidazolium hydroxide ([bmim][OH]) as a basic ionic liquid catalyst. This method has some distinct advantages such as mild reaction conditions, short reaction time and is environmentally friendly. [ABSTRACT FROM AUTHOR]