학술논문

eHydrogenation: Hydrogen‐free Electrochemical Hydrogenation.
Document Type
Article
Source
Angewandte Chemie International Edition. 9/18/2023, Vol. 62 Issue 38, p1-6. 6p.
Subject
*HYDROGENATION
*AZIDO group
*GROUP 15 elements
*NATURAL products
*DEUTERIUM
Language
ISSN
1433-7851
Abstract
Hydrogenation reactions are staple transformations commonly used across scientific fields to synthesise pharmaceuticals, natural products, and various functional materials. However, the vast majority of these reactions require the use of a toxic and costly catalyst leading to unpractical, hazardous and often functionally limited conditions. Herein, we report a new, general, practical, efficient, mild and high‐yielding hydrogen‐free electrochemical method for the reduction of alkene, alkyne, nitro and azido groups. Finally, this method has been applied to deuterium labelling. [ABSTRACT FROM AUTHOR]